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    歐盟委員會發布CLP附件VI修訂草案,54個物質統一分類受影響

    來源 瑞旭集團 作者

    ECHA風險評估委員會就引入或更新某些物質的統一分類和標簽發布意見,并在發布修訂以前,向成員國和利益相關者征集意見。本次擬采納意見的物質有54個,清單見附表。

    歐盟委員會曾收到利益相關方對1,4-苯二胺、N,N'-混合Ph、甲苯基衍生物、二丁基氧化錫的科學評估提出的質疑。經評估,額外的信息不足以質疑其科學評估。因此,引入有關物質的統一分類和標簽是適當的。

    另外,數據表明鉛塊在水中的溶解度低于鉛粉,根據法規(EC)1272/2008附件I第4部分的計算得出的鉛塊分類不夠嚴格。因此,就M因子而言,修改鉛粉已有的水生毒性分類是合適的,并對鉛塊引入不同的水生毒性分類。

    關于甲基丙烯酸甲酯的呼吸道致敏物分類,碳酸鋰、氯化鋰和氫氧化鋰作為生殖毒性物質的分類,委員會也收到了利益相關方的補充信息。由于新信息還需進一步評估,上述4種物質在現階段不應進行統一的分類和標簽。

    此次分類修訂,歐盟也給予了供應商一段過渡期,用來調整產品的標簽和包裝,并根據現有的監管要求銷售現有庫存。供應商也可以在本條例適用日期前自愿應用新的分類。本法規將會在《歐盟官方公報》上公布后第20天生效,并將在生效后的18個月后開始適用。

    附表:

    序號

    物質名稱

    1. 

    benzyl(diethylamino)diphenylphosphonium 4-[1,1,1,3,3,3-hexafluoro-2-(4-hydroxyphenyl)propan-2-yl]phenolate

    2. 

    benzyltriphenylphosphonium, salt with 4,4'-[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis[phenol] (1:1)

    3. 

    reaction mass of 4,4'-[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]diphenol and benzyl(diethylamino)diphenylphosphonium 4-[1,1,1,3,3,3-hexafluoro-2-(4-hydroxyphenyl)propan-2-yl]phenolate (1:1)

    4. 

    reaction mass of 4,4'-[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]diphenol and benzyltriphenylphosphonium, salt with 4,4'-[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis[phenol] (1:1)

    5. 

    4,4'-[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]diphenol; bisphenol AF

    6. 

    cinnamaldehyde; 3-phenylprop-2-enal; cinnamic aldehyde; cinnamal [1], (2E)-3-phenylprop-2-enal [2]

    7. 

    benfluralin (ISO); N-butyl-N-ethyl-α,α,α-trifluoro-2,6-dinitro-p-toluidine

    8. 

    3,3'-dimethylbiphenyl-4,4'-diyl diisocyanate

    9. 

    foramsulfuron (ISO); 2-{[(4,6-dimethoxypyrimidin-2-yl)carbamoyl]sulfamoyl}-4-formamido-N,N-dimethylbenzamide; 1-(4,6-dimethoxypyrimidin-2-yl)-3-(2-dimethylcarbamoyl-5-formamidophenylsulfonyl)urea

    10. 

    ethyl acrylate

    11. 

    methyl acrylate; methyl propenoate  

    12. 

    methyl methacrylate; methyl 2-methylprop-2-enoate; methyl 2-methylpropenoate

    13. 

    transfluthrin (ISO); 2,3,5,6-tetrafluorobenzyl (1R,3S)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate

    14. 

    allyl methacrylate; 2-methyl-2-propenoic acid 2-propenyl ester

    15. 

    mepiquat chloride (ISO); 1,1-dimethylpiperidinium chloride

    16. 

    triethylamine

    17. 

    di-n-butylamine

    18. 

    4-nitrosomorpholin

    19. 

    difenoconazole (ISO); 1-({2-[2-chloro-4-(4-chlorophenoxy)phenyl]-4-methyl-1,3-dioxolan-2-yl}methyl)-1H-1,2,4-triazole; 3-chloro-4-[(2RS,4RS;2RS,4SR)-4-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)-1,3-dioxolan-2-yl]phenyl 4-chlorophenyl ether

    20. 

    N,N-dimethyl-p-toluidine

    21. 

    potassium chlorate

    22. 

    sodium chlorate

    23. 

    reaction mass of 1-(2,3-epoxypropoxy)-2,2-bis ((2,3-epoxypropoxy)methyl) butane and 1-(2,3-epoxypropoxy)-2-((2,3-epoxypropoxy)methyl)-2-hydroxymethyl butane

    24. 

    metribuzin (ISO); 4-amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5(4H)-one; 4-amino-4,5-dihydro-6-(1,1-dimethylethyl)-3-methylthio-1,2,4-triazin-5-one

    25. 

    lithium carbonate [1] lithium chloride [2] lithium hydroxide [3]

    26. 

    dimethyl propylphosphonate

    27. 

    dibutyltin maleate

    28. 

    dibutyltin oxide

    29. 

    clothianidin (ISO); (E)-1-(2-chloro-1,3-thiazol-5-ylmethyl)-3-methyl-2-nitroguanidine

    30. 

    cymoxanil (ISO); 2-cyano-N-[(ethylamino)carbonyl]-2-(methoxyimino)acetamide

    31. 

    nonylphenol, branched and linear, ethoxylated (with average molecular weight < 352 g/mol) [includes ortho-, meta-, para- isomers or any combination thereof]

    32. 

    nonylphenol, branched and linear, ethoxylated (with 352 g/mol ≤ average molecular weight < 704 g/mol) [includes ortho-, meta-, para- isomers or any combination thereof]

    33. 

    nonylphenol, branched and linear, ethoxylated (with 704 g/mol ≤ average molecular weight ≤ 1540 g/mol) [includes ortho-, meta-, para- isomers or any combination thereof]

    34. 

    1-phenylethan-1-one (1-phenylethylidene)hydrazone

    35. 

    9-[2-(ethoxycarbonyl)phenyl]-3,6-bis(ethylamino)-2,7-dimethylxanthylium chloride; Basic Red 1

    36. 

    picolinafen (ISO); N-(4-fluorophenyl)-6-[3-(trifluoromethyl)phenoxy]pyridine-2-carboxamide; 4′-fluoro-6-[(α,α,α-trifluoro-m-tolyl)oxy]picolinanilide

    37. 

    diuron (ISO); 3-(3,4-dichlorophenyl)-1,1-dimethylurea

    38. 

    diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide

    39. 

    hydrogen sulphide, hydrogen sulfide

    40. 

    benzyl alcohol

    41. 

    resorcinol; 1,3-benzenediol

    42. 

    2,2',6,6'-tetrabromo-4,4'-isopropylidenediphenol; tetrabromobisphenol-A

    43. 

    a reassessment at the request of the Commission to review the harmonised classification of lead (environment) -

    44. 

    2,2'-[[3-methyl-4-[(4-nitrophenyl)azo]phenyl]imino]bisethanol

    45. 

    3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctan-1-ol

    46. 

    1,4-Benzenediamine, N,N'-mixed Ph and tolyl derivs.; Reaction mass of N-phenyl,N’-o-tolyl-phenylene diamine, N,N’-diphenyl-p-phenylene diamine and N,N’-di-o-tolyl-phenylene diamine

    47. 

    tetramethylene dimethacrylate

    48. 

    7,7,9(or 7,9,9)-trimethyl-4,13-dioxo-3,14-dioxa-5,12-diazahexadecane-1,16-diyl bismethacrylate

    49. 

    2,2'-ethylenedioxydiethyl dimethacrylate

    50. 

    bifenox (ISO); methyl 5-(2,4-dichlorophenoxy)-2-nitrobenzoate

    51. 

    4-methylimidazole

    52. 

    sulfur dioxide

    53. 

    1,2-benzisothiazol-3(2H)-one; 1,2-benzisothiazolin-3-one

    54. 

    benalaxyl (ISO); methyl N-(2,6-dimethylphenyl)-N-(phenylacetyl)-DL-alaninate

     

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